Tuesday, January 24, 2012

Packaged or bare?

Bare Anode Ingots
Last week was the Rocky Mountain Section of NACE's short course. It was the biggest turn out yet with over 300 people attending! It's a great opportunity to meet customers (and competitors), and learn more about this rusty world. Every year is a Basic CP course that goes over the basics of electrochemistry, and what the corrosion cycle is. The nugget I garnered this year has to do with sacrifical anodes. A question I always have to ask when someone orders a mag (or zinc) anode is, do you want that packaged or bare?

When we talk about anodes, we talk about the bare weight of the ingot. "I want a 17 pound mag anode," means, I want an anode with 17 pounds of magnesium. The ingot is then silver soldered for a strong connection between the lead wire and the bare metal. Some anodes--bare anodes--are then finished.

The pictures on the left show bare ingot dimensions, where
the picture on the right shows a cross-section of a packaged
anode.
For a packaged anode, the ingot is then surrounded by a backfill and a cloth bag. This adds a significant amount of weight (at least doubling it; a 17# anode becomes 50#). The backfill is a standard mix of 75% gypsum, 20% bentonite, and 5% sodium sulfate. Each part plays an important part:
  • The gypsum helps maintain a constant resistance between the anode and the structure being protected.
  • The bentonite (clay) helps retain moisture (the electrolyte) against the ingot to help make sure the ingot is what corrodes, not the metal structure.
  • The sodium sulfate helps keep the ingot from passivation, where the metal forms a film to protect itself.
The packaging of an anode obviously adds to freight costs, and the cost of the anode goes up by about 33%, but the benefits of ensuring an anode is protecting the neighboring communities explains why every specification I've worked with requires packaging.

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